I have two hubs on my network, a Philips Hue and a SmartThings. I gave up trying to get any Alexa hubs to co-exist with them and have removed all Alexa devices with internal hubs from the network. Everything just seems to operate more smoothly.
I use both Philips and Samsung (SmartThings) motion sensors, in a variety of situations, to trigger Alexa routines all the time.